教师名录
袁群惠
通讯地址:深圳市南山区西丽深圳大学城哈工大校区G栋813
电子邮件:yuanqunhui@hit.edu.cn
联系电话:0755-86244014

个人简介

申请人主要从事电化学催化电极材料相关研究。课题组前期针对环境水体中的重金属离子、酚类、抗生素等典型污染物,开展电化学传感与荧光传感材料与器件的设计与开发。在金属有机框架化合物(MOFs)衍生碳材料的理性设计、可控构筑、性能优化及传感机理等方面开展了系统深入的研究,探索了一系列基于MOF材料的新型高性能环境污染物传感检测材料。首次报道了从MOF获得多面体纳米介孔碳,并将其作为电极修饰材料应用于水中铅、镉离子同时检测的工作。该电化学传感器对铅、镉离子具有很宽的线性范围和很低的检测限。首次报道了一种通过酸蒸汽氧化方式快速、大量制备石墨烯荧光量子点的新方法,并将其应用和拓展到纯碳石墨烯量子点、氮掺杂石墨烯量子点及氮硫双掺杂石墨烯量子点的制备中,获得的量子点均对水中的重金属离子具有良好的荧光传感性能。该方法大大改进了以往酸化制备法中需使用数十倍剂量的腐蚀性酸试剂的缺陷,被评为英国皇家化学会(RSC)高被引论文。基于此工作的贡献,申请人入选2017英国皇家化学会“Top 1%高被引中国作者”榜单(2018年10月公布)。在Acc. Chem. Res.、PNAS、JACS、Chem. Eur. J.、Carbon、ACS Appl. Mater. Interfaces、Sensor. Actuat. B-Chem.、J. Mater. Chem. C、Anal. Chim. Acta、Electrochim. Acta、Analyst、Talanta等SCI期刊上发表论文近五十篇,h指数16(web of science数据)。申请人曾主持多项国家级和省部级项目,完成国家自然科学基金2项,担任本领域内多个主流国际杂志的审稿人,曾荣获中国分析测试协会一等奖。

研究方向

1. 功能分子表界面纳米结构的调控与过程研究
2. 电化学传感器
3. 二次电池、燃料电池电极材料与器件

教育经历

1997-2001  烟台大学,本科
2001-2006  中科院化学所,硕博连读
  
  

研究与工作经历

2007-2008  美国克拉克森大学(Clarkson University)化学与生命科学系,研究助理、研究助理教授
2008-2011  美国天普大学(Temple University)化学系,博士后、访问学者
2011-2016  中国科学院新疆理化技术研究所,研究员、博士生导师
2016至今  哈尔滨工业大学深圳研究生院,教授、博士生导师
  

专业资质与学术兼职

2017至今  Senior Editorial Board Members of General Chemistry

科研项目

2015-2018  国家自然科学基金面上项目
2013-2015  国家自然科学基金青年基金项目
2011-2016  中国科学院人才项目
2017-2019  深圳市高层次人才项目
2018-2020  深圳市科创委自由探索项目
2011-2015  中国科学院“西部之光”重点项目
2013-2015  新疆自治区“杰出青年”项目

科研成果及奖励

2006  中国分析测试协会一等奖(排名第一)
2018  英国皇家化学会2017 “Top 1%高被引中国作者”(2018.10)

发明专利

1. 一种改性橘子皮生物吸附剂的制备方法及用途,贾汉忠,刘明灯,李守柱,袁群惠,王传义,申请号:201210260921.2.
2. 一种镉离子荧光探针及制备方法和用途,王欢欢,王传义,袁群惠,申请号:201210411081.5.
3. 一种同时检测镉和铅离子的电化学传感器及制备方法,袁群惠,肖丽丽,周生海,申请号:201410273441.9.
4. 荧光碳量子点/聚丙烯腈纳米纤维膜的制备方法及用途,李守柱,袁群惠,王传义,申请号:201210276414.8.
5. 一种汞离子荧光探针及制备方法和用途,王欢欢,袁群惠,王传义,申请号:201410555700.7
6. 一种用于同时灵敏检测多巴胺和尿酸的电化学传感器及制备方法,袁群惠,吴淑程,干为,侯易, 专利申请号:CN201810111314.7
7. 一种用于灵敏检测重金属镉离子的电化学传感器及制备方法,袁群惠,吴淑程,干为,吴星星,王敬敏,专利申请号:CN201810113670.2
8. 负载碳量子点的介孔二氧化硅/聚丙烯腈核壳纳米纤维膜的制备及应用, 李守柱,袁群惠,周生海,,专利申请号:CN201610049047.6
9. 一种重金属吸附海绵及其制备方法和应用,李迎春,刘江,张学记,袁群惠,张波,张玉, 专利申请号:CN201610329094.6

论文及著作

[1] A highly sensitive electrochemical sensor for Cd(II) based on protic salt derived nitrogen and sulfur co-doped porous carbon. Wu, Xingxing; Wu, Shucheng; Li, Yingchun; Chen, Han; Yuan, Qunhui; Gan, Wei, Analytica Chimica Acta 2019, 1046, 115-122.
[2] Concentrated Hydrogel Electrolyte-Enabled Aqueous Rechargeable NiCo//Zn Battery Working from-20 to 50 degrees C. Wang, Hua; Liu, Jie; Wang, Jiaqi; Hu, Mengmeng; Feng, Yuping; Wang, Panpan; Wang, Yueyang; Nie, Ningyuan; Zhang, Jiaheng; Chen, Han; Yuan, Qunhui; Wu, Junwei; Huang, Yan, ACS Applied Materials & Interfaces 2019, 11, 49-55.
[3] Novel molecularly imprinted polymer (MIP) multiple sensors for endogenous redox couples determination and their applications in lung cancer diagnosis. Liu, Jie; Wang, Yuli; Liu, Xiaoxue; Yuan, Qunhui; Zhang, Yang; Li, Yingchun, Talanta 2019, 199, 573-580.
[4] MOF derived porous carbon modified rGO for simultaneous determination of hydroquinone and catechol. Chen, Han; Wu, Xingxing; Lao, Chunfeng; Li, Yingchun; Yuan, Qunhui; Gan, Wei, Journal of Electroanalytical Chemistry 2019, 835, 254-261.
[5] 3D nitrogen-doped graphite foam@Prussian blue: an electrochemical sensing platform for highly sensitive determination of H2O2 and glucose. Zhang, Yu; Huang, Bintong; Yu, Feng; Yuan, Qunhui; Gu, Meng; Ji, Junyi; Zhang, Yang; Li, Yingchun, Microchimica Acta 2018, 185.
[6] Tunable Synthesis of CoP and CoP2 Decorated 3D Carbon Nanohybrids and the Application of CoP2 Decorated One in Electrochemical Detection of Chloramphenicol in Milk and Honey. Wu, Xingxing; Lao, Chunfeng; Li, Yingchun; Yuan, Qunhui; Gan, Wei, Journal of the Electrochemical Society 2018, 165, B916-B923.
[7] Synthesis of nitrogen and sulfur co-doped yolk-shell porous carbon microspheres and their application for Pb(II) detection in fish serum. Wang, Haoqiang; Xu, Ruiyu; Chen, Han; Yuan, Qunhui, Journal of Solid State Chemistry 2018, 266, 63-69.
[8] A highly selective fluorescence sensing platform for nanomolar Hg(II) detection based on cytosine derived quantum dot. Luo, Liang; Song, Ting; Wang, Haoqiang; Yuan, Qunhui; Zhou, Shenghai, Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy 2018, 193, 95-101.
[9] Lyophobicity may not be the main driving force for long chain surfactants from the bulk phase to the interface. Liang, Yuanzhen; Zhang, Si; Wu, Wei; Yang, Fangyuan; Gan, Wei; Jia, Hangzhong; Chen, Shunli; Zhu, Xuefeng; Yuan, Qunhui, Physical Chemistry Chemical Physics 2018, 20, 10165-10172.
[10] Order-Disorder Transition of Carboxyl Terminated Chains in Polydiacetylenes Vesicles Probed by Second Harmonic Generation and Two-Photon Fluorescence. Chen, Shun-li; Zhu, Xue-feng; Yang, Fang-yuan; Pan, Xue-cong; Gan, Wei; Yuan, Qun-hui, Chinese Journal of Chemical Physics 2018, 31, 269-276.
[11] Highly sensitive electrochemical sensor for chloramphenicol based on MOF derived exfoliated porous carbon. Xiao, Lili; Xu, Ruiyu; Yuan, Qunhui; Wang, Fu, Talanta 2017, 167, 39-43.
[12] KOH assisted activation of microwave exfoliated graphite oxide for selective voltammetric determination of dopamine and uric acid in the presence of ascorbic acid. Wu, Shucheng; Xiao, Lili; Du, Zhenzhen; Wang, Haoqiang; Yuan, Qunhui; Ji, Hengxing, Journal of Electroanalytical Chemistry 2017, 804, 72-77.
[13] Ultrasound irradiated preparation of a nanosheet assembly from lariat ethers and its application as a stimuli-responsive fluorescent indicator for silver ion in aqueous solution. Wang, Huanhuan; Zhu, Xuefeng; Xu, Hongbo; Yuan, Qunhui, Sensors and Actuators B-Chemical 2017, 238, 985-991.
[14] Protic salt-based nitrogen-doped mesoporous carbon for simultaneous electrochemical detection of Cd(II) and Pb(II). Qin, Danfeng; Xu, Ruiyu; Shen, Hangjia; Mamat, Xamxikamar; Wang, Le; Gao, Shanshuang; Wang, Ying; Yalikun, Nuerbiya; Wagberg, Thomas; Zhang, Shiguo; Yuan, Qunhui; Li, Yongtao; Hu, Guangzhi, RSC Advances 2017, 7, 36929-36934.
[15] Electrochemical sensing platform based on molecularly imprinted polymer decorated N,S co-doped activated graphene for ultrasensitive and selective determination of cyclophosphamide. Huang, Bintong; Xiao, Lili; Dong, Haifeng; Zhang, Xueji; Gan, Wei; Mahboob, Shahid; Al-Ghanim, Khalid Abdullah; Yuan, Qunhui; Li, Yingchun, Talanta 2017, 164, 601-607.
[16] The behavior of hydroxide and hydronium ions at the hexadecane-water interface studied with second harmonic generation and zeta potential measurements. Gan, Wei; Wu, Wei; Yang, Fangyuan; Hu, Deping; Fang, Hui; Lan, Zhenggang; Yuan, Qunhui, Soft Matter 2017, 13, 7962-7968.
[17] N-Doped Ordered Mesoporous Carbon Originated from a Green Biological Dye for Electrochemical Sensing and High-Pressure CO2 Storage. Zhou, Shenghai; Xu, Hongbo; Yuan, Qunhui; Shen, Hangjia; Zhu, Xuefeng; Liu, Yi; Gan, Wei, ACS Applied Materials & Interfaces 2016, 8, 918-926.
[18] Graphene quantum dots: recent progress in preparation and fluorescence sensing applications. Zhou, Shenghai; Xu, Hongbo; Gan, Wei; Yuan, Qunhui, RSC Advances 2016, 6, 110775-110788.
[19] Nitrogen, Sulfur Dual-Doped Mesoporous Carbon Modified Glassy Carbon Electrode for Simultaneous Determination of Hydroquinone and Catechol. Xu, Ruiyu; Xiao, Lili; Luo, Liang; Yuan, Qunhui; Qin, Danfeng; Hu, Guangzhi; Gan, Wei, Journal of the Electrochemical Society 2016, 163, B617-B623.
[20] Time-efficient syntheses of nitrogen and sulfur co-doped graphene quantum dots with tunable luminescence and their sensing applications. Xu, Hongbo; Zhou, Shenghai; Xiao, Lili; Yuan, Qunhui; Gan, Wei, RSC Advances 2016, 6, 36554-36560.
[21] Facile one-pot synthesis and application of nitrogen and sulfur-doped activated graphene in simultaneous electrochemical determination of hydroquinone and catechol. Xiao, Lili; Yin, Jiao; Li, Yingchun; Yuan, Qunhui; Shen, Hangjia; Hu, Guangzhi; Gan, Wei, Analyst 2016, 141, 5555-5562.
[22] An efficient electrochemical sensor based on three-dimensionally interconnected mesoporous graphene framework for simultaneous determination of Cd(II) and Pb(II). Xiao, Lili; Wang, Biwei; Ji, Li; Wang, Fu; Yuan, Qunhui; Hu, Guangzhi; Dong, Angang; Gan, Wei, Electrochimica Acta 2016, 222, 1371-1377.
[23] Understanding the Different Steps of Surfactant Adsorption at the Oil-Water Interface with Second Harmonic Generation. Wu, Wei; Fang, Hui; Yang, Fangyuan; Chen, Shunli; Zhu, Xuefeng; Yuan, Qunhui; Gan, Wei, Journal of Physical Chemistry C 2016, 120, 6515-6523.
[24] Metal dependent motif transition in a self-assembled monolayer of bipyridine derivatives via coordination: An STM study. Wang, Yi; Yuan, Qunhui; Xu, Hongbo; Zhu, Xuefeng; Gan, Wei, Journal of Chemical Physics 2016, 145.
[25] In situ Magnesiothermal Synthesis of Mesoporous MgO/OMC Composite for Sensitive Detection of Lead Ions. Shen, Hangjia; Qin, Danfeng; Li, Yuzhen; Li, Shouzhu; Yang, Chi; Yuan, Qunhui; Wagberg, Thomas; Hu, Guangzhi, Electroanalysis 2016, 28, 2939-2946. [26] A green adsorbent derived from banana peel for highly effective removal of heavy metal ions from water. Li, Yingchun; Liu, Jiang; Yuan, Qunhui; Tang, Hui; Yu, Feng; Lv, Xin, RSC Advances 2016, 6, 45041-45048.
[27] Luminescent properties and sensing performance of a carbon quantum dot encapsulated mesoporous silica/polyacrylonitrile electrospun nanofibrous membrane. Li, Shouzhu; Zhou, Shenghai; Xu, Hongbo; Xiao, Lili; Wang, Yi; Shen, Hangjia; Wang, Huanhuan; Yuan, Qunhui, Journal of Materials Science 2016, 51, 6801-6811.
[28] Fabrication of a nitrogen-doped graphene quantum dot from MOF-derived porous carbon and its application for highly selective fluorescence detection of Fe3+. Xu, Hongbo; Zhou, Shenghai; Xiao, Lili; Wang, Huanhuan; Li, Shouzhu; Yuan, Qunhui, Journal of Materials Chemistry C 2015, 3, 291-297.
[29] Nanoreactor-confined synthesis and separation of yellow-luminescent graphene quantum dots with a recyclable SBA-15 template and their application for Fe(III) sensing. Xu, Hongbo; Zhou, Shenghai; Xiao, Lili; Li, Shouzhu; Song, Ting; Wang, Yi; Yuan, Qunhui, Carbon 2015, 87, 215-225.
[30] A protocol of self-assembled monolayers of fluorescent block molecules for trace Zn(II) sensing: structures and mechanisms. Xu, Hongbo; Wang, Huanhuan; Zhou, Shenghai; Xiao, Lili; Yan, Yun; Yuan, Qunhui, Rsc Advances 2015, 5, 106061-106067.
[31] One-step synthesis of isoreticular metal-organic framework-8 derived hierarchical porous carbon and its application in differential pulse anodic stripping voltammetric determination of Pb(II). Xiao, Lili; Zhou, Shenghai; Hu, Guangzhi; Xu, Hongbo; Wang, Yi; Yuan, Qunhui, Rsc Advances 2015, 5, 77159-77167.
[32] DNA derived fluorescent bio-dots for sensitive detection of mercury and silver ions in aqueous solution. Song, Ting; Zhu, Xuefeng; Zhou, Shenghai; Yang, Guang; Gan, Wei; Yuan, Qunhui, Applied Surface Science 2015, 347, 505-513.
[33] Molecular interactions at the hexadecane/water interface in the presence of surfactants studied with second harmonic generation. Sang, Yajun; Yang, Fangyuan; Chen, Shunli; Xu, Hongbo; Zhang, Si; Yuan, Qunhui; Gan, Wei, Journal of Chemical Physics 2015, 142.
[34] Simultaneous detection of Cd(II) and Pb(II) by differential pulse anodic stripping voltammetry at a nitrogen-doped microporous carbon/Nafion/bismuth-film electrode. Xiao, Lili; Xu, Hongbo; Zhou, Shenghai; Song, Ting; Wang, Huanhuan; Li, Shouzhu; Gan, Wei; Yuan, Qunhui, Electrochimica Acta 2014, 143, 143-151.
[35] Temperature dependent 2D self-assembled motif transition of copper-phthalocyanine derivates at air/HOPG interface: an STM study. Wang, Yamin; Xu, Hongbo; Wang, HuanHuan; Li, Shouzhu; Gan, Wei; Yuan, Qunhui, Rsc Advances 2014, 4, 20256-20261.
[36] Cysteine-modified orange peel for removal of Cu(II) from aqueous solutions. Liu, Mingdeng; Yuan, Qunhui; Jia, Hanzhong; Li, Shouzhu; Wang, Xiaohuan; Wang, Chuanyi, Water Science and Technology 2013, 67, 2444-2450.
[37] An STM Study of the pH Dependent Redox Activity of a Two-Dimensional Hydrogen Bonding Porphyrin Network at an Electrochemical Interface. Yuan, Qunhui; Xing, Yangjun; Borguet, Eric, Journal of the American Chemical Society 2010, 132, 5054-5060.
[38] Surface Confined Metallosupramolecular Architectures: Formation and Scanning Tunneling Microscopy Characterization. Li, Shan-Shan; Northrop, Brian H.; Yuan, Qun-Hui; Wan, Li-Jun; Stang, Peter J., Accounts of Chemical Research 2009, 42, 249-259.
[39] Fabrication and Manipulation of Molecular Nanostructure with Metal-Coordinated Compound on Solid Surfaces Investigated by STM. Chen, Ting; Yuan, Qun-Hui; Wan, Li-Jun, Acta Physico-Chimica Sinica 2009, 25, 389-400.
[40] Scanning tunneling Microscopy investigation of a supramolecular self-assembled three-dimensional chiral prism on a Au(111) surface. Yuan, Qun-Hui; Yan, Cun-Ji; Yan, Hui-Juan; Wan, Li-Jun; Northrop, Brian H.; Jude, Hershel; Stang, Peter J., Journal of the American Chemical Society 2008, 130, 8878-+.
[41] Structural comparison of self-organized adlayers of ligands and their metal-coordinated complexes on a Au(III) surface: An STM study. Yuan, Q. H.; Wan, L. J., Chemistry-a European Journal 2006, 12, 2808-2814.
[42] Controllable distribution of single molecules and peptides within oligomer template investigated by STM. Gong, Jian-Ru; Yan, Hui-Juan; Yuan, Qun-Hui; Xu, Li-Ping; Bo, Zhi-Shan; Wan, Li-Jun, Journal of the American Chemical Society 2006, 128, 12384-12385.
[43] Self-organization of a self-assembled supramolecular rectangle, square, and three-dimensional cage on Au(111) surfaces. Yuan, Q. H.; Wan, L. J.; Jude, H.; Stang, P. J., Journal of the American Chemical Society 2005, 127, 16279-16286.
[44] Mesoscopic self-organization of a self-assembled supramolecular rectangle on highly oriented pyrolytic graphite and Au(111) surfaces. Gong, J. R.; Wan, L. J.; Yuan, Q. H.; Bai, C. L.; Jude, H.; Stang, P. J., Proceedings of the National Academy of Sciences of the United States of America 2005, 102, 971-974.
[45] Self-assembled structure of alkyloxy substituted benzoic acid methyl ester on HOPG: An STM study. Yuan, Q. H.; Lu, J.; Wan, L. J.; Bai, C. L., Chinese Science Bulletin 2004, 49, 2590-2593.
[46] Ordered arrays of semi-crown ligands on an Au(111) electrode surface: in situ STM study. Pan, G. B.; Li, H. J.; Yuan, Q. H.; Chen, Y. J.; Wan, L. J.; Bai, C. L., Science in China Series B-Chemistry 2004, 47, 320-325.

会议论文及发表演说

1. 袁群惠,石墨烯量子点的纳米反应器限域合成及其铁离子荧光传感研究,第十二届全国分析化学年会, 武汉,2015, 05.
2. 袁群惠,八辛氧基铜酞菁在石墨表面自组装层温度依赖性结构变化研究, 中国化学会第十四届全国化学动力学会议, 西安,2015, 08.
3. 袁群惠,Hg(II)离子选择性吸附剂的制备及性能研究, 自然科学基金委物理化学青年学术交流研讨会, 杭州, 2013, 04.
4. Yuan QH, Li YZ. Investigation of Post-CMP Cleaners on NiP disc. 12th International CMP Symposium, Hilton Resort, Lake Placid, NY, USA. 2007, 08.
5. Yuan QH, Xing YJ, Borguet E. STM Study of Adsorption and Reaction of Organic Molecules at Charged Solid-Liquid Interfaces. Invited talk in Department of Chemistry, The University of Maryland, MD, USA. 2009, 02.
6. Yuan QH, Li YZ. Post-CMP cleaning on NiP disc. CAMP Conference of Center for Advanced Material Processing, Clarkson University, Potsdam, NY, USA. 2007, 08.

任教和任导师经历

2011.8-2016.3  中国科学院新疆理化技术研究所,研究员、博士生导师
已招收和培养硕士生5名、博士生2名,1人获国家奖学金,多人获中科院“三好学生”称号。
2016.4至今  哈尔滨工业大学深圳研究生院 教授、博士生导师
最后更新:2019-05-30 15:57:32